Experimental and theoretical investigations on the MMOF selectivity for CO2 vs. N2 in flue gas mixtures.

Molecular Simulation Studies of Flue Gas Purification by Bio-MOF

As a new branch of MOFs which are composed of biocompatible metal ions and organic ligands, bio-metal-organic frameworks (bio-MOFs) have attracted much attention recently. Bio-MOFs feature multiple Lewis basic sites which have strong interaction with CO2 molecules, thus they have great potential in the separation and purification of gas mixtures containing CO2. In this work, molecular simulatio...

Selective Mass Transport of CO2 Containing Mixtures through Zeolite Membranes

In this work, the main aspects regarding the permeation of mixtures containing CO2 and permanent gases such as H2 , N2 and CH4 through zeolite membranes have been investigated, focusing on the description of the mass transport mechanisms taking place inside the pores. First, a brief overview about the performance of the main zeolite membranes used in gas separation (e.g. DDR, CHA, AEI, FAU, etc...

Enhancement of CO2/CH4 Adsorptive Selectivity by Functionalized Nano Zeolite

In this work, we have modified a synthesized Y-type zeolite (Si/Al = 2.5), with three different amines to investigate of the influence of adsorbent’s surface modification on CO2 selectivity over CH4. The pristine and amine-functionalized NaY zeolites were characterized by X-ray diffraction (XRD), thermal gravimetric analysis (TGA), Fourier transform infrared (FT-IR), and N2 adsorption. The resu...

Optimization of parameters affecting separation of gas mixture of O2, N2, CO2 and CH4 by PMP membrane modified with TiO2, ZnO and Al2O3 nanoparticles

The application of membranes in various industries is one of the most urgent needs to reduce energy consumption and environmental pollutants as well as low investment costs in the process of separation. In this investigation, the optimization of effective parameters for separation of gas mixture of CH4, CO2, O2 and N2 is studied by modified poly(4-met...

A computational investigation on the structural features of alkanolamine solvents for CO2 capture process from power plant flue gas